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Encyclopedia · styling polymer

Carbomer

A cross-linked polyacrylic acid that turns watery formulas into clear gels; in hair gels it is mainly the thickener, not the hold agent.

Cosmetic ingredient Cost $ Safety: minor

flat hairpoor curl definition

What it is

Carbomers are high-molecular-weight cross-linked acrylic acid polymers. Neutralised with a base, they swell into a clear, stable gel. Clear wet-look hair gels typically pair carbomer with PVP or acrylic fixatives such as acrylates copolymer. That pairing is industry practice. See styling products explained.

How it works

Carbomer gels thin out when sheared and have a yield strength, and in a pharmaceutical test system their flow behaviour barely changed between pH 5 and 8 (Islam 2004). That is why a gel holds its shape in your palm yet spreads through hair.

What the studies show

  • Bench rheology: shear-thinning, yield-stress gels that are stable over pH 5 to 8 (Islam 2004). This is mechanism only.
  • In December 2023 the US FDA issued guidance on benzene-grade carbomer in drug products, and the pharmacopeia deadline for discontinuing it was extended to 2026-08-01 (Bansal 2024). This covers drugs, not cosmetics.
  • Related cross-linked alkyl acrylates were judged safe unless polymerised in benzene (Fiume 2017). We did not open a safety report specific to carbomer.
  • No hair-specific outcome study was found.

How it's used in studies

Not applicable to hair. Pharmaceutical papers use it as a gel base.

Side effects and safety

Irritation is very rare in practice. The benzene concern relates to the solvent used to make older "benzene-grade" carbomers, and modern grades use other solvents. Check the manufacturer's specification if it matters to you. Carbomer gels combined with some fixatives or salts can pill or flake.

Bottom line

Carbomer is an invisible workhorse. It explains "gel feel" and pilling, not hold. There is nothing to seek or avoid for most people. We are confident it is a thickener and moderately confident about its safety.

Studies 3

Islam MT et al. Rheological characterization of topical carbomer gels neutralized to different pH. Pharm Res. 2004

Design
other
Who
bench study

Result: Carbomer gels are shear-thinning with a yield stress and stable between pH 5 and 8.

Read the study ↗

Bansal K, Jindal AB. Risk assessment and reformulation of drug products manufactured using benzene grade carbomer. AAPS PharmSciTech. 2024

Design
review

Tested: benzene-grade carbomer in drug products

Result: Regulatory review: FDA guidance (December 2023) on benzene-grade carbomer in drug products; the USP discontinuation deadline was extended to 2026-08-01.

Read the study ↗

Fiume MM et al. Safety Assessment of Cross-Linked Alkyl Acrylates as Used in Cosmetics. Int J Toxicol. 2017

Design
review

Tested: 23 cross-linked alkyl acrylates

Result: Judged safe as used if not polymerised in benzene; data were insufficient for those that were.

Read the study ↗